The dark brown colour of myyear old half full bottle of Rodinal is nothing to worry about
Most other developers are not so flexible. I use Ilford Delta 3200 high speed film quite a lot and the best results are achieved by developing it in Ilford DD-X. DD-X comes in big 1 litre plastic bottles which is quite a lot a developer for me to use up even at 1+4 dilution. DD-X will last for up to 2 years in full bottles, but only 4 months in half full bottles. I therefore always decant it into small bottles to get the maximum shelf life. I have used DD-X that is up to 14 months old (but stored in small, full bottles) with no problems.
I decant DD-X into different size bottles to maximise shelf life
I got the little bottle in Boots (Chemist) the big one is a Tropicana Orange Juice Bottle, from McDonalds.
Of course you never know how long the developer has been on the shelf of the store you buy it from, but I think Ilford's own shelf life figures are conservative anyway.
I do some C41 Colour home developing using the Tetenal kit (not as much as I used to as I'm in a black and white phase at the moment). Unlike the black and white developers, which I use 'one shot' (pour away after one use) the Tetenal chemicals must be reused. The quoted shelf life of the made up Tetenal chemicals is 6 weeks. The last batch I used seemed to be fine even after 12 months! I keep the chemicals in tightly sealed plastic bottles in a cool dark place.
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